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可溶性多环芳烃的合成及其自组装性能研究

Synthesis and self-assembly of soluble polycyclic aromatic hydrocarbons

中文摘要英文摘要

多环芳烃分子由于其独特的理化特性和自组装性能,广泛应用于超分子材料领域。与全碳的多环芳烃相比,骨架中含有氟、氮、硫、氧等富电子或电负性强的杂原子的多环芳烃衍生物,通过改变分子的电子亲合势、偶极等在诸如晶体生长、液晶相及光电性能等方面可以呈现出独特的性质,成为一类非常有潜力的新型有机功能分子。本文设计合成了在骨架中引入硫原子的多环芳烃衍生物,并探讨了其溶解性及自组装性能。研究结果表明该化合物在溶液中能够通过分子间的π-π堆积作用自组装形成球状结构。

Polycyclic aromatic hydrocarbon (PAH) molecules have been widely applied in the supramolecular materials field due to their unique physicochemical characteristics and self-assembly properties. Compared with full carbon ones, PAH containing rich electronic or strong electronegative heteroatoms, such as fluorine, nitrogen, sulfur, oxygen, in the skeleton exhibited a different electron density, polarity and so on. PAHs have became a kind of potential organic functional molecules. Therefore, the soluble sulfur-fused PAH has been designed and synthesized in this paper. The solubility and self-assembly properties of this compound were discussed. The results showed that the PAH could self-assemble into spherical nanostructures in the solution.

向芸颉、张灯青、金武松、殷江辉、李贤英

有机化学工业高分子化合物工业

超分子化学多环芳烃自组装合成

Supramolecular chemistrypolycyclic aromatic hydrocarbonself-assemblysynthesis

向芸颉,张灯青,金武松,殷江辉,李贤英.可溶性多环芳烃的合成及其自组装性能研究[EB/OL].(2016-05-18)[2025-08-02].http://www.paper.edu.cn/releasepaper/content/201605-638.点此复制

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