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金属氧化物氧还原催化剂的研究进展

Research progress of catalysts for oxygen reduction of metal oxides

中文摘要英文摘要

用低廉的金属氧化物材料取代珍贵的铂(Pt)基电催化剂,促进燃料电池阴极的氧还原反应(ORR),对开发高性能可持续能源器件有重要意义。然而,非铂材料其较低的内在催化活性、有限的活性位点和较差的质量输运性能等问题仍然存在巨大挑战。材料的不断优化和纳米技术的不断进展使合理设计具有优化成分和精细纳米结构的催化剂成为可能,为在分子水平上提高ORR性能提供了新的机遇。本文综述了金属氧化物催化剂方面的调控进展。

It is important for developing high-performance sustainable energy devices to promote oxygen reduction reaction (ORR) of fuel cell cathode by replacing precious platinum (Pt) based electrocatalyst with cheap metal oxide material. However, the low intrinsic catalytic activity, limited active sites and poor mass transport performance of non-platinum materials still pose great challenges. Continuous optimization of materials and advances in nanotechnology have made it possible to design catalysts with optimized compositions and fine nanostructures, providing new opportunities to improve ORR performance at the molecular level. The progress in regulation of metal oxide catalysts is reviewed in this paper.

郝乙鑫、傅仁利

氢能、氢能利用化学

金属氧化物燃料电池氧还原非铂催化剂

Metal oxideFuel cellOxygen reductionNonplatinum catalyst

郝乙鑫,傅仁利.金属氧化物氧还原催化剂的研究进展[EB/OL].(2021-12-14)[2025-08-04].http://www.paper.edu.cn/releasepaper/content/202112-36.点此复制

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