镍基催化剂对污泥微波热解制生物气效能影响
Impact on biosyngas performance produced by microwave-induced catylytic pyolysis of sludge with nickel-based catalyst
为实现污水污泥减量化、无害化及资源化的目标,在微波热解污水污泥基础上,进行了镍基催化剂对制取生物气效能影响的研究。采用元素分析对污泥元素进行检测,气/质联用分析(GC-MS)和气相色谱(GC)对热解生物气的组成和含量进行测定。试验结果表明,镍基催化剂的添加对微波热解污水污泥制取生物气有较大促进作用。5%添加量与800℃热解终温条件下具有最佳催化效果:生物气中H2、CO产量最大,H2产量由29g/kg增加到35.8g/kg,提升23.4%,CO产量由302.7g/kg增加到383.3g/kg,提升26.6%;同时催化剂还能提高热能利用效率,降低热解终温,即5%添加量在700℃热解终温时可达到空白800℃时的产气效果;镍基催化剂主要在500~600℃时发挥催化作用,加快了H2和CO的释放。微波热解污泥制取的生物气具有产量大、富含H2与CO等优点,可推动污水污泥的资源化进程。
Pyrolysis of sewage sludge can achieve the goals of converting sewage sludge to resources and greatly decreasing quality. On the basis of microwave-induced pyrolysis of sewage sludge, discuss the impact on biosyngas produced by microwave-induced catylytic pyolysis of sewage sludge with nickel-based catalyst. Elementary analysis is used to measure the elements of sludge. GC and GC/MS are used to analyse on the components and yield of biosyngas. The results showed that nickel-based catalysts had significant impacts on the generation and quality of biosyngas. At 800℃ with 5% nickel-based catalyst, the production of hydrogen and carbon monoxide content reached the maximum: the production of hydrogen increased from 29g/kg to 35.8g/kg(increased by 23.4%),carbon monoxide increased from 302.7g/kg to 383.3g/kg(increased by 26.6%). Meanwhile nickel-based catalyst can improve the utilization of heat energy, making the production of biosyngas at 700℃(5% nickel-based catalyst) equal to at 800℃(no catalyst).The main working temperature range of nickel-based catalyst is 500~600℃, accelerating the release of hydrogen and carbon monoxide. Biosyngas, which is rich in hydrogen and carbon monoxide, has a big production and can help in promoting the process of sewage sludge to resources.
陈浩、左薇、吴晓燕、田禹、龚真龙
废物处理、废物综合利用能源动力工业经济生物能、生物能机械设备
微波热解污水污泥镍基催化剂生物气
microwave-induced pyrolysissewage sludgenickel-based catalystbiosyngas
陈浩,左薇,吴晓燕,田禹,龚真龙.镍基催化剂对污泥微波热解制生物气效能影响[EB/OL].(2013-05-29)[2025-08-24].http://www.paper.edu.cn/releasepaper/content/201305-457.点此复制
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