Terphenyl(bisamino)phosphines: Electron-rich Ligands for Gold-Catalysis
Terphenyl(bisamino)phosphines: Electron-rich Ligands for Gold-Catalysis
Terphenyl(bisamino)phosphines have been identified as effective ligands in cationic gold(I) complexes for the hydroamination of acetylenes. These systems are related to Buchwald phosphines and their steric properties have been evaluated. Effective hydroamination was noted even at low catalyst loadings and a series of cationic gold(I) complexes has been structurally characterized clearly indicating stabilizing effects through gold-arene interactions.
Christian Hering-Junghans、Christoph Schmidt、Malte Fischer、Andr?§| Schumann、Jan-Erik Siewert
Christian Hering-JunghansChristoph SchmidtMalte FischerAndr?§| SchumannJan-Erik Siewert
有机化学工业精细化学工业制药化学工业
Gold ComplexesPhosphine Ligands TuningHydroamination reactionsgold catalysisterphenyl derivatives
Christian Hering-Junghans,Christoph Schmidt,Malte Fischer,Andr?§| Schumann,Jan-Erik Siewert.Terphenyl(bisamino)phosphines: Electron-rich Ligands for Gold-Catalysis[EB/OL].(2020-07-09)[2025-08-18].https://chemrxiv.org/engage/chemrxiv/article-details/60c74d7bbdbb89e4b8a399d6.点此复制
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