含单氧化双膦配体的异金属发光簇合物
Luminescencent Heterometallic Cluster Cu14Ag12 Containing Diphosphine Monoxide Ligands
通过[tBuC6H4C≡CAg] 和 [Cu2(dppp)2(MeCN)2](BF4)2 在空气中反应合成了[Ag12Cu14(C≡CC6H4But)22(dppp)2(dpppo)2](BF4)4。 该簇合物是一个含十二个一价银和十四个一价铜的异金属发光化合物。双膦配体在反应过程中发生了部分氧化。
he largest heterometallic AgI-CuI cluster [Ag12Cu14(C≡CC6H4But)22(dppp)2(dpppo)2](BF4)4 comprising twelve silver(I) and fourteen copper(I) centers was synthesized by reacting [tBuC6H4C≡CAg] with [Cu2(dppp)2(MeCN)2](BF4)2; the cluster is held together by alkynyl, diphosphine and diphosphine monoxide (formed through in situ partial oxidation) ligands.
王泉明、贾建华
化学晶体学
铜晶体结构簇合物发光银
opperrystal structurelusterLuminescenceSilver
王泉明,贾建华.含单氧化双膦配体的异金属发光簇合物[EB/OL].(2010-03-01)[2025-08-04].http://www.paper.edu.cn/releasepaper/content/201003-8.点此复制
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