普鲁士蓝类嵌入正极材料的发展与挑战
Recent Progress and Challenges in the Development of Prussian Blue Analogues as New Intercalation Cathode Materials
作为一类具有开放离子通道、多种氧还反应位点、化学稳定的晶格结构, 普鲁士蓝化合物具有潜在的高电压、高容量和循环稳定性质, 原则上适合于作为多种离子的嵌入正极材料. 基于本课题组近年来的研究工作, 本文分析了普鲁士蓝结构特征与离子嵌入行为之间的构效关系, 简要介绍了作为锂离子、钠离子及其他多价金属离子(镁、铝、锌、钙等)嵌入正极的研究进展, 并对目前存在的问题提出了可能的解决方案, 以推动新一代嵌入材料体系及相关新型二次电池的发展.
s a large family of the lattices with open framework structure, abundant redox-active sites and chemically stable structures, Prussian blue and its analogues (PBAs) can serve in principle as promising insertion cathode materials for a variety of metal ions. This paper reviews the recent progress on the development of PBAs compounds as Li+, Na+ and other multivalent ions (Mg2+, Al3+, Zn2+, Ca2+ and etc.) insertion cathodes, discusses the relationship between the crystal structure of PBAs and their ion insertion behaviors and briefly analyzes the possible strategies for the problems present in the battery applications of PBAs, aiming at promoting the development of a new type of cathode host materials for next generation advanced batteries.
吴晨、杨汉西、钱江锋
材料科学电化学工业
普鲁士蓝嵌入正极锂离子电池钠离子电池多价金属离子电池
Prussian blue intercalation cathodes lithium ion batteries sodium ion batteries multivalent ion batteries
吴晨,杨汉西,钱江锋.普鲁士蓝类嵌入正极材料的发展与挑战[EB/OL].(2017-04-25)[2025-06-25].http://www.paper.edu.cn/releasepaper/content/201704-458.点此复制
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