溶剂热合成三维开放骨架结构配位聚合物Zn3(C9H3O6)2(C9H4O6)(N(CH3)4)2(H3O)Cl
Solvthermal Synthesis of a 3-Dimentional Open Framework Zn3(C9H3O6)2(C9H4O6)(N(CH3)4)2(H3O)Cl
本文通过溶剂热方法合成了一种具有三维开放骨架结构的配位聚合物Zn3(C9H3O6)2(C9H4O6)(N(CH3)4)2(H3O)Cl。通过X射线单晶衍射测定其空间群为P21/n，晶胞参数a=1.7996(5)nm，b=1.4186(3)nm，c=2.0497(3)nm，α= 90.00(0)°，β= 91.00(9)°，γ= 90.00(0)°。该化合物是由一个三核锌簇和1，3，5-均苯三甲酸通过配位氧原子连接构成的三维开放骨架。
ompound Zn3(C9H3O6)2(C9H4O6)(N(CH3)4)2(H3O)Cl was synthesized under solvthemal conditions, and its crystal structure was determined by using single crystal X-ray diffraction. The compound crystallizes in monoclinic space group P21/n with a=1.7996(5)nm, b=1.4186(3)nm, c=2.0497(3)nm, α= 90.00(0)°, β= 91.00(9)°, γ= 90.00(0)°. Three zinc centers link with each other through 1,3,5-benzenetricarboxylic acid ligand to form a 3-dimentional open framework.
于吉红、李激扬、徐如人、徐进、潘勤鹤
化学晶体学
配位聚合物 无机-有机杂化材料 开放骨架 溶剂热合成
coordination polymer Inorganic-organic hybrid framework open framework solvthermal synthesis
于吉红,李激扬,徐如人,徐进,潘勤鹤.溶剂热合成三维开放骨架结构配位聚合物Zn3(C9H3O6)2(C9H4O6)(N(CH3)4)2(H3O)Cl[EB/OL].(2008-01-07)[2025-08-16].http://www.paper.edu.cn/releasepaper/content/200801-164.点此复制
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