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氧化锌纳米草阵列的制备、结构及场发射性能研究

Growth, structure and field emission property of ZnO nanograsses

中文摘要英文摘要

本文利用碳热还原方法在金催化剂的辅助下成功地在硅衬底上合成了氧化锌纳米草阵列。对样品进行表征发现,在氧化锌纳米草的顶端存在有合金颗粒,这说明了氧化锌纳米草的生长是典型的气-液-固生长过程。在生长过程中,衬底附近较高的原子浓度对于纳米草的形成起着非常重要的作用。氧化锌纳米草的发光光谱说明其具有良好的结晶性。同时对样品进行了场发射性能的测试分析,氧化锌纳米草具有较低的阈值电场及较高的发射电流。研究表明氧化锌纳米草阵列的形貌结构以及在衬底上的分布密度对其场发射性能产生了良好的影响作用。

In this paper, ZnO nanograss array is fabricated on silicon substrates using thermal chemical vapor transport and condensation (CVTC) with gold nanoparticles as metal catalyst. It is found that the alloying cataly droplets are located at the tip of ZnO nanograsses, impling the growth of ZnO nanograss array is a typical vapor- liquid- solid process. In the growth process, the higher ZnO concentration of the growth ambience is suggested to plays a crucial role for the formation of ZnO nanograsses. The luminescence spectrum prove that ZnO nanograss array has good crystallinity. The field emission property of as- prepared ZnO nanograss arrays are characterized. The low turn- on electronic field and the higher current density are achieved with ZnO nanograss arrays as the emitters. It was suggested that the morphology, structure and distribution density of ZnO nanograss arrays play a crucial role for its excellent field emission property.

董海媚、杨玉华

材料科学物理学晶体学

氧化锌纳米结构纳米草阵列场发射

ZnONanograssField emission

董海媚,杨玉华.氧化锌纳米草阵列的制备、结构及场发射性能研究[EB/OL].(2013-01-31)[2025-08-02].http://www.paper.edu.cn/releasepaper/content/201301-1255.点此复制

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