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锰-萘-1,4-二酸化合物的离子热合成以及其π-π作用和模板作用的协同效应

ooperation of π-π Interaction and Template Effect in Ionothermal Synthesis of Multi-Dimensional Manganese Naphthalene-1,4- Dicarboxylate Compounds

中文摘要英文摘要

本文报道了从两个基于锰-萘-1,4-二酸层状化合物和两个锰-萘-1,4-二酸三维网状化合物的离子热合成和结构鉴定,并对有机配体和离子液体之间的π-π作用和模板作用的协同效应做了深入探讨。

wo layered manganese naphthalene-1,4-dicarboxylate compounds based on the paddle-wheel Mn2(COO)4 motifs, (EMIm)[Mn(ndc)Br] and (HMIm)[Mn(ndc)Br], and two three-dimensional networks (RMIm)[Mn2(ndc)2(OAc)] (RMIm = BMIm and HMIm ) were prepared from various ionic liquids. Significant relationship of π-π interactions and template effect are found between the naphthalene part of organic ligands and IL imidazolium rings

黄琳娜、孟岩、刘俊良、林卓佳、童明良

化学晶体学

无机材料化学离子热合成π-π作用模板作用

Ionothermalπ-π InteractionManganese

黄琳娜,孟岩,刘俊良,林卓佳,童明良.锰-萘-1,4-二酸化合物的离子热合成以及其π-π作用和模板作用的协同效应[EB/OL].(2012-03-09)[2025-08-18].http://www.paper.edu.cn/releasepaper/content/201203-312.点此复制

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