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一种通过测定十二烷基苯磺酸根含量鉴别地沟油的新型荧光探针

New Supramolecular Fluorescence Probe for Distinguishing waste oil by Determination of Dodecylbenzenesulfonic Anion

中文摘要英文摘要

十二烷基苯磺酸常存在于地沟油中,可通过测定一般地沟油里边其含量,以间接的鉴别地沟油。本文以硫脲基团和1,8-萘酰亚胺衍生物为模块,设计并合成出了一种三脚架型荧光探针分子,通过荧光测试发现其荧光强度随十二烷基苯磺酸根浓度增加而增强,并且其响应浓度极限达到1 ppm。进一步研究表明,探针分子与十二烷基苯磺酸根通过氢键作用而改变探针分子芳环堆积方式而引起荧光性质上的变化。该方法灵敏性高,具有较好抗干扰性,且操作简便,快速,可用于进行对食用油和地沟油的鉴别。

odecylbenzenesulfonic anion (DBSA) is often found in waste oil, which indicates the possibility of distinguishing waste oil by determination of DBSA. For this purpose, a new supramolecular fluorescence sensor based on tris(thiourea) and 1,8-naphthanlimide derivative moieties was designed and synthesized. Fluorescence spectra of the sensor with addition of dodecylbenzenesulfonic anion showed evident fluorescence enhancement due to their PET quenching system triggered by host-guest hydrogen-bonding interaction, which demonstrated that a new method to distinguish waste oil with the tripodal sensor via fluorescence spectroscopy can be established. Through a series of experiments, this method was found to be simple, effective and practicable.

陈根庭、黄华容

油脂化学工业

荧光探针硫脲氢键十二烷基苯磺酸地沟油

Fluorescence probeThioureaHydrogen-bondDodecylbenzenesulfonic anionWaste oil

陈根庭,黄华容.一种通过测定十二烷基苯磺酸根含量鉴别地沟油的新型荧光探针[EB/OL].(2013-04-12)[2025-08-11].http://www.paper.edu.cn/releasepaper/content/201304-285.点此复制

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