动态力学热分析在芳纶纸中的应用研究
pplication Research on Dynamic Mechanical Properties of Poly(m-phenyleneisophthalamide)
研究了间位芳纶自制热压纸的动态力学性质,同时与杜邦T410纸的动态力学性质进行了对比。使用低结晶度、低定向性的样品在20℃~+500℃范围,110HZ频率和升温速率为3℃/min的条件下测定动态力学性质。DMA温度谱图上随着温度由低至高,自制芳纶热压纸经历了玻璃态、高弹态、粘流态三种不同的力学状态,各反映不同的分子运动模式。杜邦T410纸的储能模量和玻璃化转变峰均高于自制芳纶热压纸,表明杜邦T410纸具有较高的抵抗外力和变形的能力、较好的刚度,分子链自由运动困难,移动所需要的能量比较大。
he dynamic mechanical properties of PMIA-Pulp applied paper were investigated. At the same time, the dynamic mechanical properties of DuPont T410 paper were compared. Measurements of the dynamic mechanical properties were carried out on samples of low crystallinity and low orientation over a temperature range from 20 to +500℃ at a frequency of 110 Hz, at a heating rate of 3℃/min. As the temperature from low to high, three different mechanical states with glassy state, rubber state and fluid state were appeared on DMA temperature curve. It responses the different mode of molecular motion. Storage modulus and glass transition peak of DuPont T410 paper are higher than the self-made applied paper. This is mean DuPont T410 Paper has a high resistance to external forces and deformation capacity, good rigidity. It's molecular chain freedom movement difficult and the energy required to move relatively larger.
路金杯、张美云、张素风、李涛
化学纤维工业高分子化合物工业
芳纶纤维动态热力分析储能模量损耗因子
PMIADMAstorage modulusmechanical loss factor
路金杯,张美云,张素风,李涛.动态力学热分析在芳纶纸中的应用研究[EB/OL].(2010-09-17)[2025-08-04].http://www.paper.edu.cn/releasepaper/content/201009-389.点此复制
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