生物质基水凝胶的研究进展
Reaearch Progress of Biomass-based Hydrogels
目前,石油资源危机不断加剧,以生物质为原料制备水凝胶的研究逐渐引起人们关注。生物质资源具有来源广、可再生、无毒性和良好生物相容性等优点,将生物质转化为高值化的材料具有重要的意义。水凝胶是一种亲水但不溶于水的高分子聚合物,是一类集吸水、保水、缓释于一体的功能高分子材料,广泛应用于工业、农业、医药和生物工程材料领域。本文综述了木质纤维主要组分(纤维素、半纤维素、木质素)、壳聚糖、淀粉及蛋白质基等水凝胶的研究进展,探讨它们通过氢键、静电力及化学键合等结合方式如何制备水凝胶三维网络结构,以及这些水凝胶的应用。
With the depletion of fossil fuel and the concern for environmental protection, the development of sustainable materials from lignocellulosic biomass is receiving increased attention. The biomass resources have excellent properties, such as biodegradability, bio-compatibility, and non-toxicity. The developments of biodegradable materials for substituting non-biodegradable materials have become the subject of great interests in material fields. Hydrogels are water-swollen polymeric materials that maintain a distinct three-dimensional structure, which attract continuously increased attention due to their capacity to hold water, flexibility, resilience, and ability to release incorporated agents, and stand out as popular depletion material candidates in a number of important applications, including tissue engineering, scaffolds, drug delivery systems, and food compounders. The hydeogels can be formed by cross-linking polymer chains. The cross-linkings of these polymers are a result of covalent, hydrogen bonding, van der Waals forces or physical entanglements. Hydrogels prepared with different crosslinking methods present different response to the environments such as temperature, pH, light, magnetic. This paper reviews the research progress of hydrogels based on the lignocellulosic components (cellulose, hemicelluloses, and lignin), chitosan, starch, and protein. The preparing mechanism of hydrogels was also discussed, such as hydrogen bonding, electrostatic, and chemical bonding. In addition, the applications of the hydrogels such as pharmaceutical, drug delivery, biosensors, artificial skin and mussels, oil industry, agriculture, water treatment, and textile industries were disscussed. ).
孙润仓、彭锋、关莹
生物工程学生物科学现状、生物科学发展细胞生物学
生物质材料水凝胶研究进展应用
biomasshydrogelresearch progressapplication
孙润仓,彭锋,关莹.生物质基水凝胶的研究进展[EB/OL].(2014-10-28)[2025-08-16].http://www.paper.edu.cn/releasepaper/content/201410-347.点此复制
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