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首页|氧化脱氢法合成异戊烯的较大能量集成及换热网络设计优化研究

氧化脱氢法合成异戊烯的较大能量集成及换热网络设计优化研究

Research on Large Energy Integration and Heat Exchange Network Design Optimization of Oxidative Dehydrogenation Synthesis of Isoamylene

中文摘要英文摘要

该项目采用氧化脱氢法合成异戊烯,最后通过精馏塔和多级分离器进行分离纯化,获得化学纯度的异戊烯主产物和环戊烷副产物,年产量为19.8万吨。在本文中,我们使用Aspen Energy Analyzer V11.0软件来设计和优化整个过程的能量集成和换热网络设计及优化,以寻找最节能的方法以最小化能耗。通过采用双级有机朗肯回收技术和热泵技术节能创新节约能耗。其中,双级有机朗肯循环技术利用氢气分离塔内分离出含有优质冷能的氢冷源,通过冷源与河中河水之间的热交换节省了公共工程量,从而达到节能的目的。热泵技术充分利用了精馏塔塔顶和塔底之间的温度差异很小。通过改变蒸汽的温度,可以将可交换能量的流股充分利用,从而增加了可回收能量的比例,并实现了更大程度的节能。通过这些优化措施,转换后的节省能量为99.74MW,需要64.48MW的冷公用工程,和35.26MW的热公用工程,从而实现更大程度的能源回收。

he project adopts oxidative dehydrogenation method to synthesize isoamylene, and uses rectification tower and multi-stage separator to separate and purify finally to obtain chemical purity isoamylene main product and cyclopentane by-product, with an output of 198,000 tons/year. In this paper, we use Aspen Energy Analyzer V11.0 software to design and optimize the energy integration and heat exchange network of the overall process, looking for the most energy-saving measures to minimize energy consumption. By adopting two-stage organic Rankine recycling technology and heat pump technology. Among them, the two-stage organic Rankine cycle technology uses the hydrogen cold source containing high-quality cold energy separated by the hydrogen separation tower, and saves the amount of public works through heat exchange between the cold source and the river water in the river near the site. So as to achieve the purpose of energy saving. The heat pump technology makes full use of the rectification tower with a small difference between the top and the bottom of the tower. By changing the temperature of the steam, it is possible to exchange heat for streams that could not exchange heat, thereby increasing the ratio of recoverable energy and achieving a greater degree Energy saving. Through this optimization measure, the converted energy saving is 99.74MW, which requires 64.48MW of cold utilities and 35.26MW of heat utilities, which achieves a greater degree of energy recovery.

左辉、何明洁、史建俊、李朝旭、程晨、曹雪

能源动力工业经济热力工程、热机有机化学工业

计算机技术异戊烯换热网络设计及优化双级有机朗肯热泵技术

omputer technologyisoamyleneenergy integration and heat exchang network designtwo-stage organic Rankineheat pump distillation

左辉,何明洁,史建俊,李朝旭,程晨,曹雪.氧化脱氢法合成异戊烯的较大能量集成及换热网络设计优化研究[EB/OL].(2020-10-10)[2025-08-18].http://www.paper.edu.cn/releasepaper/content/202010-6.点此复制

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