食用菌菌渣转化的多孔碳作为一种高性能吸附剂去除水中双酚A的研究
Edible Fungus Dregs Derived Porous carbon as High Performance Adsorbents to Decontaminate the Bisphenol A
双酚A(BPA)是一种内分泌干扰物之一,它能模仿人体激素影响人体正常的新陈代谢。随着环境问题日趋严重,甚至在饮用水中都能检测到BPA的存在。活性炭吸附是去除水中有机污染物的重要手段。本文使用食用菌菌渣作为原料,通过简单的炭化和活化过程得到比表面积高达3878.3 m3/g的多孔活性炭材料。材料制备过程简单、易操作,并且用到的化学试剂只有氢氧化钾与盐酸,整个制备过程绿色环保。该多孔碳材料对水中的BPA表现出良好的吸附性能,吸附动力学研究结果表明该吸附行为符合拟二级动力学模型;在探究pH对吸附量的影响实验中,发现该碳材料在酸性和中性条件下均有着较好的吸附性能,但在碱性条件下吸附量明显下降。对该过程的等温吸附模型进行探究发现该吸附过程能很好符合Langmuir吸附模型,并且在25℃时达到最大吸附量1248mg/g。
s one of the Endocrine-disrupting chemicals, bisphenol A (BPA) can impersonate the natural hormones and disturb .metabolic processes of human body. As environmental problems become more severe, BPA is detected even in drinking water. Adsorption by activated carbon is an important way to remove organic pollutants from water. In this work, theporous carbon material with the specific surface area of 3878.2 m3g-1 was obtained by the carbonization and activation processes. Preparation process is facile and easy to operate, and the chemical reagents used in whole process are only potassium hydroxide and hydrochloric acid, which achieves the green enviromental protection. These porous carbon materialsexhibited excellent performance for absorbing BPA in water. The adsorption kinetics showed that the adsorption behavior was in accordance with the pseudo-second-order kinetic model.The adsorption performance of these porous carbon in the acidic and neutral conditions is outstading, and the maximum quantity can reachas high as 1249 mg/g, whereasthat in alkaline conditions decreased significantly. The adsorption model of the process was also explored and demonstrated that the adsorption process was well consistent with the langmiur adsorption model.
汪萍、陶维、曹菲菲、刘恋、顾江江、成建
环境污染、环境污染防治废物处理、废物综合利用环境科学理论
物理化学食用菌菌渣多孔碳吸附双酚A
physical chemistryedible fungus slagporous carbonadsorbentbisphenol A
汪萍,陶维,曹菲菲,刘恋,顾江江,成建.食用菌菌渣转化的多孔碳作为一种高性能吸附剂去除水中双酚A的研究[EB/OL].(2017-05-17)[2025-08-03].http://www.paper.edu.cn/releasepaper/content/201705-1103.点此复制
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