Mn3(C10H6NO6)2(H2O)6] H2O配位聚合物的合成结构与表征
Synthesis Structure and Characterization of [Mn3(C10H6NO6)2(H2O)6] H2O
以H4L1（H4L1 = 5-(Bis-carboxymethyl-amino)-isophthalic acid）为有机配体，在水热条件下成功合成一例配位聚合物：[Mn3(L2)2(H2O)6]oH2O(1)(H3L2 = 5-Carboxyamino-isophthalic acid)(配体H3L2由H4L1脱羧而得)。对其进行元素分析、红外光谱、XRD、热重分析等表征。结构分析表明，1属于单斜晶系，C2/c空间群，是由Mn2簇与有机配体、Mn原子构筑而成的2D层状结构，相邻的层状结构之间通过氢键作用形成一个3D的超分子结构。
novel complex ([Mn3(L2)2(H2O)6]oH2O) was hydrothermally synthesized and characterized by X-ray single crystal structure analysis, elemental analyses, IR, XRD, TGA. Complex 1 is of monoclinic, space group C2/c. The structural analysis results showed that a 2D layer is constructed by the assemble of Mn2 clusters, organic ligands, and Mn atoms, meanwhile, a 3D supramolecular structure is formed through hydrogen bonding between the adiacent layers.
李志猛、牛成、王芙香、张才灵、智霞、陈明、任国建
化学晶体学
配位聚合物氢键超分子结构水热合成
omplexHydrogen bondSupramolecularSolvothermal Synthesis
李志猛,牛成,王芙香,张才灵,智霞,陈明,任国建.Mn3(C10H6NO6)2(H2O)6] H2O配位聚合物的合成结构与表征[EB/OL].(2016-07-28)[2025-08-03].http://www.paper.edu.cn/releasepaper/content/201607-276.点此复制
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