硫酸渣复合球团还原焙烧法制备高品位磁铁精矿
Making High Quality Magnetite Concentrate from Pyrite Cinder by Composite Pellet Reduction-roasting and Magnetic-separation
硫酸渣复合球团还原焙烧-磁选试验研究结果表明:以铁品位低(TFe45.56%)、铜和硫含量高(Cu0.19%,S1.45%)的某硫酸渣为原料,添加复合添加剂5%,在圆盘造球机上制备复合球团,将生球干燥后进回转窑还原焙烧,喷入300kg/t煤,在700℃~800℃下还原焙烧20min,将还原焙烧后产物通过两段球磨、四段磁选工艺,可得到铁品位高(TFe66.23%)、Cu、S含量低(Cu0.048%,S0.053%)的优质磁铁精矿,其铁回收率达到73.32%,铜脱除率可达74.73%,硫脱除率达到96.34%。关键技术为复合粘结剂促进铁氧化物的还原及铜、硫等杂质的转化,在磁选分离过程中被脱除。使用此新工艺,能综合利用硫酸渣中铁资源,扩大钢铁工业原料来源,具有良好的经济效益、环保效益及广阔的推广应用前景。
new technology of Composite Pellet Reduction-roasting and Magnetic-separation (CPRM) has been developed for utilization of pyrite cinder, a common by-product in vitriol industry. Pyrite cinder, assaying 45.56% Fe, 0.19% Cu and 1.45% S, was pelletized with the addition of 5% composite agent in balling disc. Green balls after drying were reduced at 700℃~800℃ for 20min with 300kg/t pulverized coal injection in rotary kiln. After two-stage ball-grinding and four stages magnetic separation, magnetite concentrate with iron grade of 66.23% Fe and containing 0.048% Cu and 0.053% S were made. And iron recovery of 73.32%, desulphurization degree of 96.34% and decoppering degree of 74.73% were achieved. Key technique is that composite agent can accelerate reduction of Fe2O3 and transfer copper and sulphur into water-soluble inorganic salts, which were removed during wet magnetic concentration. Using this CPRM technology can fully utilize pyrite cinder and produce high quality magnetite concentrate as iron-bearing feed for steel industry, which will help to solve the pollution of pyrite cinder and extend raw material sourcing for Chinese steel industry.
徐小锋、翟勇、朱德庆、崔瑜、唐艳云、李建、潘建
冶金技术炼铁废物处理、废物综合利用
综合利用硫酸渣复合球团还原焙烧磁选脱铜脱硫
multipurpose utilizationpyrite cindercomposite pelletreduction roastingmagnetic-separationdesulphurization and decoppering
徐小锋,翟勇,朱德庆,崔瑜,唐艳云,李建,潘建.硫酸渣复合球团还原焙烧法制备高品位磁铁精矿[EB/OL].(2006-09-19)[2025-08-10].http://www.paper.edu.cn/releasepaper/content/200609-273.点此复制
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