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用于电解水析氢的CoP催化剂的研究进展

Research Progress on CoP as hydrogen evolution electrocatalyst

中文摘要英文摘要

氢能相对于传统化石能源具有热值高,燃烧无污染的优点,电解水法可以利用太阳能、风能等制备高纯度的氢气,实现资源高效利用。过渡金属磷化物(Transition metal phosphides,TMPs)是取代电催化剂铂(Pt)的最有发展前景的非贵金属催化材料之一,其中磷化钴(CoP)因其独特的物理化学性质,比如富含磷元素和良好的导电性而被广泛研究。目前有各种研究工作集中在提高TMPs的电催化性能,而针对CoP提高催化性能的系统性研究工作却很少。因此,本文从磷化钴的制备方法和提升电催化性能的先进策略两方面总结介绍了当前针对CoP基电解水析氢催化剂的研究进展。

ompared with traditional fossil energy, hydrogen energy has the advantages of high calorific value and no pollution from combustion. Electrolytic water method can make use of solar energy and wind energy to prepare high-purity hydrogen and realize efficient utilization of resources.Transition metal phosphides (TMPs) are one of the most promising non-noble metal catalytic materials to replace electrocatalyst platinum (Pt). Among them, cobalt phosphide (CoP) has been widely studied due to its unique physicochemical properties, such as phosphorus rich and excellent electrical conductivity..At present, there are various studies focusing on improving the electrocatalytic performance of TMPs, but there are few systematic studies on improving the catalytic performance of CoP.Therefore, this paper summarizes the current research progress of cop-based electrolytic water hydrogen evolution catalysts from two aspects of preparation methods of cobalt phosphide and advanced strategies for improving electrocatalytic performance.

于然波、王祖民、孟程

氢能、氢能利用电化学工业

过渡金属磷化物磷化钴析氢反应电催化

transition metal phosphidecobalt phosphidehydrogen evolution reactionelectrocatalysis

于然波,王祖民,孟程.用于电解水析氢的CoP催化剂的研究进展[EB/OL].(2022-03-24)[2025-08-02].http://www.paper.edu.cn/releasepaper/content/202203-354.点此复制

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