压电薄膜的摩擦、磨损性能
Friction and wear performance of the piezoelectric film
具有准同型相界组分的0.5Ba(Ti0.8Zr0.2)O3- 0.5(Ba0.7Ca0.3)TiO3 (BZT-0.5BCT)陶瓷,表现出优异的铁电、压电性能,作为一种具有潜在应用前景的无铅压电材料得到广泛关注。本文采用溶胶-凝胶方法在Si(100)基底上制备了BZT-0.5BCT压电薄膜.使用原子力显微镜和扫描电子显微镜测量得到样品的形貌图,形貌图表明该方法制备的无铅压电薄膜表面光滑,晶粒大小均匀、呈半球形,直径为80-100 nm,厚度为1.7μm,膜的内部有气孔.摩擦力实验表明,压电薄膜样品与硅针尖之间存在静电力的作用,导致其摩擦力远大于硅针尖与SiO2之间的摩擦力,但是两者的摩擦系数基本相同。划痕实验表明,BZT-0.5BC薄膜具有很强的法向承载能力,但是切向抗磨损能力差,样品的平均弹性模量为23.64 5GPa,其硬度为2.7~4 GPa,两者均略低于压电陶瓷(PZT)材料的体态值。
s a lead-free piezoelectric material with potential application, 0.5Ba(Ti0.8Zr0.2)O3- 0.5(Ba0.7Ca0.3)TiO3 (BZT-0.5BCT) ceramics which has morphotropic phase boundary (MPB) composition deserves lots of attention due to its excellent ferroelectric and piezoelectric properties. BZT-0.5BCT lead-free piezoelectric film is synthesized on a Si (100) substrate by Sol-Gel process. A topography of the film measured using an atomic force microscopy and a scanning electron microscopy shows that the surface of the prepared film is smooth, and the grain is hemispheric and of 80-100 nm in diameter. The film is 1.7 μm in thickness, with pores inside. Friction experiments show that the friction between the silicon tip and the piezoelectric film is much larger than that between the silicon tip and the SiO2 substrate, because of an existence of the electrostatic force between the film and the silicon tip. However, the friction coefficients obtained are approximately equal. Nano-scratch experiments show that, the BZT-0.5BCT film has a high normal carrying capacity, but a poor tangential wear resistance. The average elastic modulus of the film is 23.64 5GPa, and its hardness is 2.7~4 GPa, both slightly lower than that of the bulk value in PZT ceramics.
王增梅、张艳、郭新立、毕可东、陈云飞
物理学材料科学电子元件、电子组件
BZT-BCT薄膜纳米摩擦力纳米压痕纳米划痕
BZT-BCTnano-frictionnanoindentaionnano scratch tester
王增梅,张艳,郭新立,毕可东,陈云飞.压电薄膜的摩擦、磨损性能[EB/OL].(2013-01-07)[2025-07-25].http://www.paper.edu.cn/releasepaper/content/201301-304.点此复制
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