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新型手性亲核催化剂DMAP衍生物的研究进展

Progress of Chiral DMAP Derivatives as Novel Nucleophilic Catalysts

中文摘要英文摘要

手性DMAP(4-Dimethylaminopyridine,4-二甲胺基吡啶)衍生物作为具有较高催化活性和对映选择性的新型手性亲核催化剂,已经在多种不对称催化反应中得到应用,并取得了很好的研究成果。目前,手性DMAP衍生物化学的研究正成为催化不对称合成领域中一个十分活跃和引人注目的研究热点。本文综述了手性DMAP衍生物化学近几年的研究进展。

hiral DMAP derivatives have been employed in catalytic asymmetric reactions as chiral nucleophilic catalysts with excellent activity and enantioselectivity. At present, studies on the applications of chiral DMAP derivatives has been regarded as one of the most remarkable fields in catalytic asymmetric reactions. This review describes the development of chiral DMAP derivatives during recent years.

张万斌、谢芳、张振锋、孙黎

化学精细化学工业制药化学工业

亲核催化剂手性DMAP衍生物不对称催化反应

nucleophilic catalystchiral DMAPcatalytic asymmetric reactions

张万斌,谢芳,张振锋,孙黎.新型手性亲核催化剂DMAP衍生物的研究进展[EB/OL].(2007-07-02)[2025-08-16].http://www.paper.edu.cn/releasepaper/content/200707-21.点此复制

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