一个由Waugh-型多阴离子与稀土离子构筑的超分子化合物的结构及表征
Synthesis and characterization of a new 3D supramolecular structure constructed by Waugh-type polyoxoanion and lanthanide ions
在常规水溶液中，通过Waugh-型多阴离子[MnIVMo9O32]6-与稀土离子Nd3+的反应，得到了一个由[MnIVMo9O32]6-与{Nd(H2O)6}3+单元构筑的三维超分子化合物：[(CH3)4N]2Nd[HMnMo9O32]•6H2O (1)。同时还通过元素分析、红外光谱、紫外可见光谱、热重以及单晶X射线衍射等对该化合物结构和物理化学性质进行了研究。
new 3D supramolecular structure [(CH3)4N]2Nd[HMnMo9O32]•6H2O (1) has been obtained in aqueous solution by reaction of the Waugh-type polyoxoanion [MnMo9O32]6- with Nd3+ ions, and characterized by IR, UV, element analysis, TG and single-crystal X-ray analysis. The crystal data for compound 1: Cubic, space group Fm-3m, a = b = c = 1.65891(1) nm, α = β = γ = 90.00(0)°，V = 4.5653(9) nm3，Z = 4.
谭华桥、王恩波
化学晶体学
Waugh-型多金属氧酸盐稀土单晶结构
Waugh-type polyoxoanionLanthanideSingle-crystal structure
谭华桥,王恩波.一个由Waugh-型多阴离子与稀土离子构筑的超分子化合物的结构及表征[EB/OL].(2010-01-26)[2025-08-16].http://www.paper.edu.cn/releasepaper/content/201001-1073.点此复制
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