纤维结构染料敏化太阳能电池的制备及其应用
Preparation and application of fibered dye-sensitized solar cells
随着物联网技术的兴起,可穿戴电子设备得到了迅速发展,其供电问题也日益突出。传统太阳能电池多为平板结构,不适合舒适穿戴。近年来飞速发展的纤维结构染料敏化太阳能电池具有柔性、轻质、可编织等特点,有望成为一种极具发展前景的可穿戴移动电源。为了制备长尺寸低缺陷的纤维结构染料敏化太阳能电池,以铜丝作为基底,首先设计连续电镀装置,在铜丝纤维的表面利用电镀工艺成功镀上一层金属锰,解决了铜丝能级不匹配的问题。其次,设计种子层连续电沉积装置,制备出致密均匀的氧化锌种子层,为氧化锌纳米阵列的生长提供合格的晶种。接着,通过电加热辅助成膜法改善了电解质层连续涂覆工艺,制备出平整均匀的碘化亚铜电解质,得到纤维光阳极。最后将金丝作为对电极成功组装了纤维结构太阳能电池,经过优化后的器件实现了1.3%的转换效率。进一步利用飞梭、刺绣等方法,将纤维电池制备成可穿戴太阳能发电织物,并且可以应用到智能家居、户外运动等多个场景,为未来可穿戴能源织物的商业化应用提供了很好的解决思路。
With the rise of the Internet of Things technology, wearable electronic devices have been rapidly developed, and their power supply problems are becoming increasingly prominent. Traditional solar cells are mostly flat structure, not suitable for comfortable wear. In recent years, dye-sensitized solar cells with fiber structure have the characteristics of flexibility, light weight and braided, and are expected to become a promising wearable mobile power supply. In order to prepare long size and low defect dye-sensitized solar cells with fiber structure, a continuous electroplating device was designed with copper wire as the base, and a layer of manganese metal was successfully plated on the surface of copper wire by electroplating process, which solved the problem of mismatch of copper wire energy levels. Secondly, a continuous electrodeposition device of seed layer was designed to prepare a dense and uniform zinc oxide seed layer, which provides qualified seed seeds for the growth of zinc oxide nanoarrays. Then, the continuous coating process of electrolyte layer was improved by electric heating assisted film forming method, and the smooth and uniform cuprous iodide electrolyte was prepared, and the fiber photoanode was obtained. Finally, the fiber structure solar cell is successfully assembled with gold wire as the counter electrode, and the conversion efficiency of 1.3% is achieved after optimization. Further use of flying shuttle, embroidery and other methods, fiber batteries are prepared into wearable solar power fabric, and can be applied to smart home, outdoor sports and other scenarios, providing a good solution for the future commercial application of wearable energy fabric.
范兴、钟佳华
光电子技术半导体技术材料科学
染料敏化太阳能电池连续化制备发电织物可穿戴。
ye-sensitized solar cellsContinuous preparationPower fabricWearable.
范兴,钟佳华.纤维结构染料敏化太阳能电池的制备及其应用[EB/OL].(2024-05-13)[2025-08-02].http://www.paper.edu.cn/releasepaper/content/202405-70.点此复制
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