Synthesis and Characterization of a Novel Coordination Complex Based on Fluorescein
novel coordination complex, {[Cd2(C20H10O5)2(H2O)4]·10H2O}n, has been synthesized based on fluorescein (2-(6-hydroxy-3-oxo-3H-xanthen-9-yl) benzoic acid) and systematically characterized by elemental analysis, infrared (IR) spectrum, thermo gravimetric analysis (TGA), powder X-ray diffraction (PXRD) and single-crystal X-ray diffraction. Compound 1 crystallizes in monoclinic, space group P2/n with a = 20.428(5), b = 8.084(2), c = 21.689(5) ?, β = 96.360(5)o, Mr = 993.46, V = 3559.7(15) ?3, Z = 4, Dx = 1.845 g/cm3, μ = 1.276 mm-1, F(000) = 1974.0, GOOF = 1.044, λ(MoKα) = 0.71073 ?, the final R = 0.0553 and wR = 0.1720 for 7245 observed reflections with I > 2σ(I).
novel coordination complex, {[Cd2(C20H10O5)2(H2O)4]10H2O}n, has been synthesized based on fluorescein (2-(6-hydroxy-3-oxo-3H-xanthen-9-yl) benzoic acid) and systematically characterized by elemental analysis, infrared (IR) spectrum, thermo gravimetric analysis (TGA), powder X-ray diffraction (PXRD) and single-crystal X-ray diffraction. Compound 1 crystallizes in monoclinic, space group P2/n with a = 20.428(5), b = 8.084(2), c = 21.689(5) , = 96.360(5), Mr = 993.46, V = 3559.7(15) 3, Z = 4, Dx = 1.845 g/cm3, = 1.276 mm-1, F(000) = 1974.0, GOOF = 1.044, (MoK) = 0.71073 , the final R = 0.0553 and wR = 0.1720 for 7245 observed reflections with I > 2(I).
ZHANG Guan-Hua、JIANG Xiao-Yu、LU Can-Zhong、WU Xiao-Yuan、WANG Sa-Sa
化学晶体学
crystal structurecoordination complexfluorescein
ZHANG Guan-Hua,JIANG Xiao-Yu,LU Can-Zhong,WU Xiao-Yuan,WANG Sa-Sa.Synthesis and Characterization of a Novel Coordination Complex Based on Fluorescein[EB/OL].(2017-11-05)[2025-08-02].https://chinaxiv.org/abs/201711.00158.点此复制
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