基于d10金属-巯基吡啶酸体系的结构多样性和反应性
Structural Diversity and Reactivity of d10 Metal-(4-pyridylthio)acetate System
该文报道了四个Zn(II)/Cd(II)与4-吡啶巯基乙酸在水热/溶剂热条件下反应得到的配合物及其晶体结构。有趣的是在化合物1合成中观察到了4-吡啶巯基乙酸的S-C(sp2)断裂，形成的[SCH2CO2]2-与Zn(II)形成配位。
he hydrothermal synthesis and crystal structures of four coordination polymers, are reported. They are based on (4-pyridylthio)acetate and its derived ligand. The derived ligand was generated from an in situ C(sp2)-S bond cleavage of (4-pyridylthio)acetate. In these compounds, versatile intermolecular interactions play an important role in the formation of three-dimensional supramolecular networks in the solid state.
童明良、林卓佳、郑凌玲、张月华、胡升、王静
化学晶体学无机化学工业
无机化学水热合成配位聚合物原位S-C键断裂
coordination polymerhydrothermal reactionin-situ S-C cleavage
童明良,林卓佳,郑凌玲,张月华,胡升,王静.基于d10金属-巯基吡啶酸体系的结构多样性和反应性[EB/OL].(2012-03-09)[2025-08-02].http://www.paper.edu.cn/releasepaper/content/201203-311.点此复制
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