基于多金属氧酸盐构筑的三维超分子网络结构
hree-Dimensional Supramolecule Network based on Polyoxometalate
本文通过利用[H3PMo12O40]，咪唑和Zn离子在水热条件下合成了一例多酸基无机-有机杂化化合物，Zn2(Imidazole)8(PMo12O40)o2H2O（1）。化合物1是由Keggin型多阴离子和Zn的配位聚合物构筑的三维超分子网络。
new polyoxometalate derivative Zn2(Imidazole)8(PMo12O40)o2H2O（1） was synthesized by using the hydrothermal conditions with the reaction involving [H3PMo12O40], Zn(Ac)2o3H2O, Imidazole, and H2O.The structure analysis indicates that 1 containing the Keggin polyoxoanion [PMo12O40] and zinc -organic cations which are connected into an extended 3D supramolecular structure through N-HoooO and C-HoooO multipoint hydrogen bonding interactions.
周恩龙、王新龙、苏忠民、黄鹏
化学晶体学
多金属氧酸盐水热合成无机-有机杂化材料
Polyoxometalateshydrothermal synthesisorganic-inorganic hybrid materials
周恩龙,王新龙,苏忠民,黄鹏.基于多金属氧酸盐构筑的三维超分子网络结构[EB/OL].(2014-01-03)[2025-08-11].http://www.paper.edu.cn/releasepaper/content/201401-153.点此复制
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