水相钯催化2-苯基吡啶氮氧化合物导向的C(sp2)-H活化单芳基化反应
Pd(II)-Catalysed Monoarylation of 2-Phenylpyridine N-Oxides with Iodobenzene in Water
本文实现了水相中钯催化2-苯基吡啶导向的C(sp2)-H活化芳基化的过程,具有较高的区域选择性,只生成单芳基化的产物,产率高达91%。广泛的底物范围突出了催化剂的灵活性,并且提出了该反应的反应机理。
Pd(II)-catalysed activation and arylation of C(sp2)-H bond directed by pyridine N-oxide in water is achieved with high regioselectivity to form monoarylated products in yields up to 91%. The wide substrate scope highlights the flexibility of the catalyst.The reaction mechanism is proposed.
周向葛、张伟
有机化学工业精细化学工业制药化学工业
有机化学钯催化2-苯基吡啶氮氧化物水
Organic ChemistryPalladiumCatalysis2-Phenylpyridine N-OxideWater
周向葛,张伟.水相钯催化2-苯基吡啶氮氧化合物导向的C(sp2)-H活化单芳基化反应[EB/OL].(2016-05-27)[2025-08-02].http://www.paper.edu.cn/releasepaper/content/201605-1389.点此复制
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