硅氧烷基卟啉的合成及表征
Syntheses and Characterizations of Porphyrins Modified by Organosilanes
本文首次将三甲基氯硅烷、乙烯基二甲基氯硅烷和二苯基甲基氯硅烷接枝到四羟基苯基卟啉上，制得三种新型卟啉衍生物。采用质谱、核磁、元素分析和红外光谱表征了它们的结构并对它们的溶解性能进行研究。同时研究了不同取代基团卟啉、不同中心金属离子四羟基卟啉的紫外-可见光谱，还进行了荧光光谱分析。
In this paper, three new porphyrin derivatives were synthesized by modification of tetrahydroxylphenylporphyrin with chlorotrimethylsilane, chlorodimethylvinylsilane and chloro(methyl)diphenylsilane. The products were characterized by 1H-NMR, ESI-MS, elemental analysis and IR spectra. Solubility of products was investigated. The effects of different substitute group and central metal ion on UV-Vis spectra were studied and fluorescence spectra were studied.
邱化玉、来国桥、李美江、沈永嘉、蒋剑雄、吕素芳
有机化学工业
卟啉 改性 硅氧烷基 合成 表征
Porphyrin modified siloxane group synthesis characterization
邱化玉,来国桥,李美江,沈永嘉,蒋剑雄,吕素芳.硅氧烷基卟啉的合成及表征[EB/OL].(2006-12-14)[2025-08-18].http://www.paper.edu.cn/releasepaper/content/200612-234.点此复制
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