基于P3HT:PCBM光伏电池的倒置结构和正置结构的研究
Investigation of organic photovoltaic cells and that with an inverted architecture based on P3HT:PCBM active layer
通过制备基于P3HT:PCBM的空穴和电子单载流子,分析出P3HT:PCBM的导电类型是空穴导电,通过制备基于P3HT:PCBM的正置倒置四种光伏电池,对比得出倒置结构比正置结构效率更高。利用I-V测试分析了器件结构为ITO/ZnO/P3HT:PCBM/ MoO3(10nm)/Al(70nm)的倒置有机太阳能电池的载流子运输机制,通过I-V,我们计算出了串联电阻、理想因子、势垒高度这些电学参数,分别是48.23 Ω、1.6和0.8eV。利用光照下的I-V测试,我们得到了该电池的开路电压、短路电流、填充因子和能量转化效率分别是0.57V、 8.2mA/cm2、61% , 2.9%.
We analyzed the conductive type of organic photovoltaic cell based on the P3HT: PCBM active layer, through the single charge carrier device. By preparation of four different cells include the normal cells and inverted cells, we came to a conclusion that the inverted cells shown advantage. The charge transport properties of ITO/ZnO/P3HT-PCBM/MoO3/Al organic device with an inverted architecture have been investigated by using current-voltage (I-V) and capacitance-voltage(C-V) techniques. The electrical parameters like series resistance Rs, ideality factor n, and barrier height to be 48.23 Ω,1.6 and 0.8 eV had been analyzed using I-V. The open circuit voltage Voc, short circuit current density Jsc, fill factor FF, PCE values for the organic solar cell are found to be, 0.57V, 0.74mA, 61%, 2.9%, respectively.
杜智杰、王利刚、刘晨曦、梁泽山、史绍华、李军、程传辉
能源动力工业经济
有机太阳电池倒置结构能量转化效率载流子运输
organic solar cellinverted architecturePCEcharge transport
杜智杰,王利刚,刘晨曦,梁泽山,史绍华,李军,程传辉.基于P3HT:PCBM光伏电池的倒置结构和正置结构的研究[EB/OL].(2012-03-15)[2025-08-03].http://www.paper.edu.cn/releasepaper/content/201203-489.点此复制
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