卟啉纳米组装和仿生催化

Porphyrin is the analogue of metalloenzyme with excellent optical and electrochemical properties. In biological systems, in order to realize the biofunction and biocatalysis, many metalloenzymes aggregate to form suprastructure with nanosize. Thus, it is significant to orderly assemble porphyrins to mimic the function of metalloenzyme. In this review, the systhysis of porphyrins, assembly of porphyrin and biosensing of porphyrin-nanomaterial composite are highlighted, and open a new venue for the development of novel electrochemical and photoelectrochemical biosensor.