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一种新型可降解β-环糊精基水凝胶对重金属离子的去除作用研究

novel biodegradable β-cyclodextrin-based hydrogel for the removal of heavy metal

中文摘要英文摘要

本论文制备了一种用于去除水溶液中的Cd2+、Pb2+和Cu2+的新型可降解β-环糊精基水凝胶(CAM),其为典型的三维网状结构且表现出优良的去除金属离子性能。文中探讨了初始pH、吸附剂用量及初始金属离子浓度等试验参数的影响。其吸附等温曲线数据符合Freundlich 动力学方程。在相同条件下,CAM对金属离子的吸附容量顺序为Pb2+ >Cu2+>Cd2+;干凝胶对Pb2+ 、Cu2+和Cd2+的最大吸附容量分别为210.6mg/g、116.41 mg/g和98.88 mg/g;褐腐菌对树脂的生物降解效率可达79.4%。高吸附容量和动力学结果表明CAM能作为一种可替代的重金属离子吸附剂。

novel biodegradable β-cyclodextrin-based gel (CAM) was prepared and applied in the removal of Cd2+, Pb2+ and Cu2+ ions from aqueous solutions. CAM hydrogel exhibited a typical three-dimensional network structure and an excellent performance for heavy metal removal. The effects of different experimental parameters, such as initial pH, adsorbent dosage and initial metal ion concentration were investigated. The adsorption isotherm data was fitted well to the Freundlich model. The adsorption capacity order was Pb2+>Cu2+>Cd2+ under the same conditions. The maximum adsorption capacities in terms of mg/g dry gel were 210.6 for Pb2+, 116.41 for Cu2+, and 98.88 for Cd2+ respectively. The biodegradation efficiency of the resin reached 79.4 % in Gloeophyllum trabeum. The high adsorption capacity and kinetics results indicated that CAM can be used as an alternative adsorbent to remove the heavy metal.

刘守新、黄占华、张斌

环境污染、环境污染防治生物科学现状、生物科学发展高分子化合物工业

β-环糊精吸附剂生物降解吸附重金属去除

β-CyclodextrinAdsorbentBiodegradableAdsorptionHeavy metal removal

刘守新,黄占华,张斌.一种新型可降解β-环糊精基水凝胶对重金属离子的去除作用研究[EB/OL].(2013-01-25)[2025-08-17].http://www.paper.edu.cn/releasepaper/content/201301-1046.点此复制

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