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o3O4多孔纳米带的无模板法制备及其增强的锂离子电池性能研究

emplate-free fabrication of Co3O4 porous nanobelts from nanorods and their enhanced lithium-ion battery performance

中文摘要英文摘要

本文采用无模板水热法合成了Co3O4多孔纳米带,该结构作为负极材料显著提高了锂离子电池的性能,其可逆容量高达1388 mAh/g,初始库仑效率达84.7%,并具有优良的循环能力,也明显优于Co3O4纳米棒的锂离子电池的性能。这主要是因为多孔纳米带比纳米棒的嵌锂能力更高,体积变化更小,并且不会发生团聚。本实验结果为制备一维多孔纳米结构提供了一个新的方法,并暗示了一维多孔纳米结构可作为高性能锂离子电池的负极材料的候选者。

o3O4 porous nanobelts are fabricated from nanorods by a template-free hydrothermal method. Enhanced lithium-ion battery performance is obtained from Co3O4 porous nanobelts. The reversible capacity is up to 1388 mAh/g, the initial coulomb efficiency is 84.7 %, and the cyclability is excellent. Lithium-ion battery performance of porous nanobelts is much higher than that of nanorods. Such a behavior is attributed to more efficient Li insertion, less volume change and no agglomeration of porous nanobelts. The present results open a way for fabrication of porous 1D nanostructures and imply that porous 1D nanostructures are good candidates for high performance lithium-ion battery anodes.

陈朝辉、薛欣宇、邢丽丽

电化学工业

纳米材料氧化钴锂离子电池负极

NanomaterialsCobalt oxideLithium-ion batteryAnode

陈朝辉,薛欣宇,邢丽丽.o3O4多孔纳米带的无模板法制备及其增强的锂离子电池性能研究[EB/OL].(2012-03-29)[2025-08-18].http://www.paper.edu.cn/releasepaper/content/201203-798.点此复制

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