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蒙脱石对乙基钾黄药-铅复合污染体系的吸附平衡与动力学

dsorption equilibrium and kinetics of potassium ethyl xanthate-lead combined pollutants on montmorillonite

中文摘要英文摘要

为揭示黄药-重金属复合污染体系的环境行为,以蒙脱石为吸附剂进行静态吸附试验,探讨了乙基钾黄药-铅复合污染体系的吸附平衡与动力学特征。结果表明,乙基钾黄药在蒙脱石上的吸附作用很微弱,它通过与Pb2+反应形成悬浮态物质而严重影响Pb2+在蒙脱石上的吸附作用,使Pb2+的吸附速率常数由10.40 gomg-1omin-1提高到54.76 gomg-1omin-1,而平衡吸附量( )则由9.80 mgog-1降低到4.27mgog-1。影响程度随着乙基钾黄药浓度的升高而增大,随着Pb2+浓度、pH值和蒙脱石投加量的升高而减弱。研究结果可为黄药-重金属复合污染环境的治理提供重要参考。

dsorption equilibrium and kinetics of potassium ethyl xanthate-lead combined pollutants to montmorillonite by static adsorption experiments were investigate to reveal environmental behavior of xanthate and heavy metals under a combined pollution system. The results showed that adsorption of potassium ethyl xanthate on montmorillonite was slight. Adsorption of Pb2+ to montmorillonite was seriously affected in the presence of potassium ethyl xanthate owing to a suspended product of the reaction between Pb2+ and potassium ethyl xanthate, adsorption rate constant increasing from 10.40 to 54.76 gomg-1omin-1,while equilibrium adsorption capacity ( ) decreasing from 9.80 to 4.27mgog-1.The impact degree improved with the increase of potassium ethyl xanthate concentration, whereas reduced with the increase of Pb2+ concentration, pH value, and montmorillonite dosage. The findings may serve as an important reference for the control of xanthate and heavy metals combined pollution.

李彦文、向垒、黄献培、莫测辉、吴小莲、梁嘉华、郝艳、屈向龙

环境污染、环境污染防治无机化学工业金属元素无机化合物化学工业

蒙脱石黄药污染控制吸附等温线动力学

montmorillonitepotassium ethyl xanthateeadpollution controladsorption isothermskinetics

李彦文,向垒,黄献培,莫测辉,吴小莲,梁嘉华,郝艳,屈向龙.蒙脱石对乙基钾黄药-铅复合污染体系的吸附平衡与动力学[EB/OL].(2010-12-09)[2025-08-02].http://www.paper.edu.cn/releasepaper/content/201012-250.点此复制

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