恒电位沉积法制备Cu掺杂Cu-CoS碱性析氢催化剂
Preparation of Cu-doped Cu-CoS alkaline hydrogen evolution catalyst by potentiostatic deposition
现有制氢方法中,电解水具有产物纯度高、方法简便、污染较小等优点,但其贵金属催化剂(Pt/C或 IrO2等)资源不足、价格昂贵,非贵金属催化剂存在过电位高、稳定性差等缺点。钴基化合物催化活性高、稳定性好、成本相对较低,极具应用前景。本文采用恒电位电沉积法在泡沫铜表面原位生长了Cu掺杂的CoS(Cu-CoS)碱性析氢催化剂,结果表明Cu掺入CoS后提升了催化剂的催化性能和导电性,增大电化学活性表面积并促使表面呈现出超疏气状态,展示出优秀的电解水催化性能:达到-10 mA/cm2电流密度所需的过电位为69 mV,Tafel斜率为58.56 mV/dec,稳定性测试60 h后电位仅增加45 mV。
mong the existing hydrogen production methods, electrolyzed water has the advantages ofhigh product purity, simple method and less pollution, but its shortcomings such as high overpotential, poor stability and expensive commercial catalysts (Pt/C, IrO2, etc.) need to be solved urgently.Cobalt-based compounds have high catalytic activity for electrolyzing water. In this paper, an efficient alkaline hydrogen evolution catalyst, Cu-CoS, was grown in situ on the surface of copper foam bypotentiostatic electrodeposition. The results show that the conductivity of the material is improved, theelectrochemical active surface area is increased, and the surface is super-hydrophobic. The overpotential required for Cu-CoS to reach the current density of ?10 mA/cm2is 69 mV, the slope of tafel is 58.56 mV/dec, and the potential increase is 45 mV after 60 h of stability test.
段泽威、雷惊雷
氢能、氢能利用电化学工业化学工业概论
物理化学碱性析氢oS掺杂
Physical chemistryalkaline hydrogen evolutionCoSdoped
段泽威,雷惊雷.恒电位沉积法制备Cu掺杂Cu-CoS碱性析氢催化剂[EB/OL].(2023-05-24)[2025-07-09].http://www.paper.edu.cn/releasepaper/content/202305-201.点此复制
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