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PH值对改性膨润土吸附Cr3+、Cr6+的影响

he impact of PH on the modified Montmorillonite adsorption

中文摘要英文摘要

利用有机改性剂的有机分子、离子、聚合物代替水化阳离子进入膨润土层间,以价键、离子键、偶极键以及范德华力与之结合,从而形成有机膨润土或有机膨润土复合物。本文选用膨润土原矿,样品细磨提纯后钠化,利用十八烷基三甲基氯化铵进行了有机改性,得到了重金属吸附剂。试验通过静态吸附实验考察了膨润土改性前后pH对 和 吸附量的影响。研究结果表明,膨润土经有机改改性后,由于其层问距,比表面积,唧孔融等均增大,所以在相同条件下膨润土对Cr3+、Cr6+的吸附量可分别由改性前的75%、79%提高到改性后的95%、97%。同时得到了最佳吸附时的PH值。

Using organic modifiers of organic molecules, ions, the polymer instead of hydration come into the bentonite interlayering cation to covalent bond, ionic bond, bond dipole, as well as with the combination of van der Waals forces to form the organic bentonite or organic expansion Run-soil complex.In this writing,Montmorillonite was modified by treating with octadecyl trimethyl ammonium chloride after grinding purification and Na-activatio- n,and then the heavy metal sorbent was available.Then through static experiment study the of the modified Montmorillonite’s absorption of .The results of thesis indicate that the sorption of Cr3+ and Cr6+of montmorillonite changed from 75%and 79%to 95%and 97%under the same condition. At the same time,The optimum PH for the adsorption areindicated.

翟付群、杨丹、张瑾、夏成娇

环境污染、环境污染防治

膨润土有机改性重金属离子吸附

MontmorilloniteModifiedHeavy Metaldsorption

翟付群,杨丹,张瑾,夏成娇.PH值对改性膨润土吸附Cr3+、Cr6+的影响[EB/OL].(2009-06-05)[2025-08-16].http://www.paper.edu.cn/releasepaper/content/200906-199.点此复制

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