大共轭体系的N-芳基吡咯并[3，4d]四硫富瓦烯衍生物的合成及其电化学性质
Synthesis and Electrochemical Property of π- conjugation extended N-Aryl pyrrolo[3,4-d]tetrathiafulvalene Derivatives
一系列大共轭体系的N-芳基吡咯并[3，4d]四硫富瓦烯衍生物（3a-d）通过4，5-二乙巯-1，3-二硫杂-2酮和N-芳基-1，3-二硫杂[4，5c]吡咯-2-硫酮（10a-d）交叉缩合被合成，后者由4，5-二溴甲基-1，3-二硫杂-2-硫酮（7）和芳香胺化合物（8a-d）闭环反应得到。循环伏安法研究结果表明：与先前文献报道的N-烷基吡咯并[3，4d]四硫富瓦烯衍生物（2a-d）相比，目标化合物3a-d 具有与之相当或更低的半波电势。
series of extended-conjugation N-Aryl pyrrolo [3,4-d] annulated tetrathiafulvalene derivatives (3a-d)were synthesized via cross coupling of 4,5-diethyl- thio-1,3-dithiole-2- one with N-aryl-(1,3)-dithiolo[4,5-c]pyrrole-2- thiones (10a-d), the later were obtained by the ring closing reaction of 4,5-bis(bromomethyl)-1,3-dithiole-2- thione (7) and aromatic amines(8a-d). We also studied electrochemical behavior of 3a-d by means of Cyclic Voltammetry. All these compounds have comparable or lower half-wave potentials than those of N-alkyl-pyrrolo[3,4-d] annulated tetrathiafulvalene derivatives (2a-c) which have been reported previously .
尹炳柱、杨永华、丛志奇
有机化学工业电化学工业精细化学工业
有机导体，大共轭体系四硫富瓦烯，电子供体，循环伏安法
organic conductor extended-conjugation tetrathiafulvalene electron donor Cyclic Voltammetry
尹炳柱,杨永华,丛志奇.大共轭体系的N-芳基吡咯并[3，4d]四硫富瓦烯衍生物的合成及其电化学性质[EB/OL].(2004-02-13)[2025-08-16].http://www.paper.edu.cn/releasepaper/content/200402-39.点此复制
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