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电刷镀制备Ni-TiO2纳米复合镀层微观结构及其腐蚀电化学行为

Microstructure and Corrosion Electrochemical Behavior of Ni-TiO2 Nanocomposite Coating Prepared by Electro-Brush Plating

中文摘要英文摘要

通过电刷镀的方法在Q235低碳钢上制备出Ni-TiO2纳米复合镀层,为获得性能优异的镀层,本文研究了复合镀液中纳米颗粒的加入量及不同的表面活性剂对镀层性能的影响。采用扫描电镜SEM对复合镀层的表面形貌进行分析,采用极化曲线研究了纳米复合镀层在3.5%NaCl溶液中的腐蚀电化学行为。结果表明:与纯Ni镀层相比Ni-TiO2纳米复合镀层晶粒更加细小,空隙率更低,阳离子表面活性剂分散镀液所得镀层效果最为显著;复合镀液中纳米TiO2含量为10g/L时,复合镀层的耐腐蚀性能最优;纳米颗粒含量相等的情况下,阳离子表面活性剂分散镀液所得镀层具有最好的耐腐蚀性能。

Ni-TiO2 nanocomposite coatings with various contents of TiO2 nanoparticles and surfactants were prepared on Q235 low carbon steel by electro-brush plating. In order to obtain the performance excellent of coating, in this article the influence of different surfactants and various contents of TiO2 nanoparticles in plating bath were investigated. The surface microstructure of composite coatings was studied by using SEM. The corrosion electrochemical behavior of Ni-TiO2 nanocomposite coating in 3.5%NaCl solution was studied by polarization curve. The results showed that Ni-TiO2 nanocomposite coatings have smaller grain and lower porosity compared to pure Ni coating. The best coating was made by cationic surfactant to disperse bath. While TiO2 nanoparticle content was 10g/L in plating bath, the coating had the best corrosion resistance. And the coating had the best corrosion resistance by cationic surfactant to disperse bath while plating bath have the same TiO2 nanoparticle content.

沈承金、朱振

电化学工业金属学、热处理材料科学

纳米复合镀层Ni-TiO2电刷镀表面活性剂极化曲线

Nanocomposite coatingNi-TiO2Brush platingSurfactantPolarization curve

沈承金,朱振.电刷镀制备Ni-TiO2纳米复合镀层微观结构及其腐蚀电化学行为[EB/OL].(2011-07-26)[2025-08-23].http://www.paper.edu.cn/releasepaper/content/201107-390.点此复制

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