重金属Cu2+污染土渗透特性试验研究
Experimental study on permeability properties of clay contaminated by Cu2+
研究了重金属Cu2+离子的侵入对土体渗透特性的影响。以人工配置的CuCl2溶液作为渗透液,采用三联式柔性壁渗透仪在室内开展了两种工况下污染土渗透试验,分别考虑了围压和渗透污染液浓度对土体渗透性的影响。试验结果表明,配制的CuCl2溶液浓度保持恒定时,渗透液无论采用纯净水还是CuCl2溶液,土体渗透系数均随着施加围压的增大而减小,但是相同围压作用下CuCl2溶液作为渗透液,测得土体的渗透系数小于纯净水作用的渗透系数,并且随着围压的增大,渗透系数的减小量呈现出逐渐缩小的趋势,直至围压超过600kPa后流体特性对土体渗透性的影响不大。施加围压相同而渗透液浓度不同的情况下,土体渗透系数随着CuCl2溶液浓度的增加先急剧减小随后则逐渐增大。微观结构分析结果表明,CuCl2溶液作为渗透液时土体渗透系数与纯净水渗透存在差异的主要原因是缘于重金属Cu2+改变了粘土的内部结构,影响了粘土的孔隙大小,从而造成了宏观渗透性的差异。
his paper mainly concentrates on the effect of Cu2+ erosion to the permeability properties of soil. In this paper, the leachate was chosen by artificial CuCl2 solution, and a serious of experiment were conducted to study permeability properties of contaminated soil under two different conditions using the triple-type flexible wall permeameter, through which the influence of confining pressure and polluted concentration of penetrating fluid on the soil permeability properties was analyzed. The experimental results have showed that when CuCl2 solution concentration was kept constant, regardless of penetrating fluid was pure water or CuCl2 solution, permeability coefficient of clay decreased with the increase of confining pressure, but under the same confining pressure the permeability coefficient of CuCl2 solution as leachate was less than that of the pure water as leachate, and with the increase of confining pressure, the reduction of permeability coefficient was gradually decreased until properties of fluid have little impact on the permeability of soil when the confining pressure was more than 600kPa. When confining pressure was kept constant but polluted concentration of penetrating fluid was different, the permeability coefficient of clay decreased rapidly at first and then gradually increased with the increased of CuCl2 solution concentration. The results of Micro-structure analysis have showed that the permeability coefficient of clay was different when the penetrating liquid was pure water or CuCl2 solution, the reason was that Cu2+ erosion could change the structure of the clay and has influence on the pore size in the soil samples, thus resulting in the differences in the macroscopic permeability.
李红艳、师玉敏、张志红
环境污染、环境污染防治
污染土重金属渗透特性微观结构
contaminated soilheavy metalpermeability propertiesmicro-structure
李红艳,师玉敏,张志红.重金属Cu2+污染土渗透特性试验研究[EB/OL].(2014-02-28)[2025-07-18].http://www.paper.edu.cn/releasepaper/content/201402-647.点此复制
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