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α-淀粉酶对地下水反硝化中SOC材料性能的改进

Performance Improvement of SOC Materials by α-amylase for In-situ Denitrification in Groundwater

中文摘要英文摘要

地下水硝酸盐污染因其对安全饮水和人类健康长期潜在的危险而引起了世界范围的广泛关注。原位生物反硝化是较为理想的脱氮方法,但面临地下水中缺乏有机碳源作为电子供体的难题。本研究制备了可用于PRB反硝化墙中的SOC(缓释有机碳源)材料,并通过静态实验对其释碳性能进行评价和改进。以淀粉和PVA为原料,并根据添加剂成份制备得到GPVAS和GEPVAS两类材料。研究结果表明材料静态碳释放过程符合二级反应动力学,其中Cm和K值分别表征其释碳能力和速度。GPVAS-40具有最低的Cm和K值。同时随α-淀粉酶活力增加,材料Cm和K值均迅速增加,且当酶活力低于0.05u/g时,K值与酶活力呈显著线性相关关系。因此,释放过程具有可控性,一定程度解决目前存在的COD残留问题。SOC材料具有潜力成为适宜的原位反硝化过程中碳源物质。

Nitrate pollution problems of groundwater have drawn comprehensive attention in many parts of the world for their perennial and potential danger to human health. In-situ biological denitrification was considered to be a promising method to remove excessive nitrate, but restricted by lack of carbon source materials. This research was designed to manufacture and identify SOC (Slow-releasing Organic Carbon-source) materials as appropriate electron donor used in PRB (Permeable Reactive Barrier). GPVAS and GEPVAS series were produced by blending starch and PVA (Poly Vinyl Alcohol) together, and their performance was detected through static batch experiments. The results showed that the carbon releasing process followed the law of second order kinetics, with the parameters Cm and K representing the releasing capability and speed, which were both the lowest of GPVAS-40. Both Cm and K values would ascend rapidly with augmenting of α-amylase content, and K was linearly correlated to U (activity of amylase) when U was lower than 0.05u/g. Consequently, the process was controllable, which solved the problem of COD residue to some extent. SOC materials were suggested to be potential and suitable carbon sources for in-situ denitrification treatment.

王允、张大奕、张旭、周贵中、李广贺

环境污染、环境污染防治环境科学技术现状环境生物学

地下水 反硝化 SOC

denitrification groundwater SOC

王允,张大奕,张旭,周贵中,李广贺.α-淀粉酶对地下水反硝化中SOC材料性能的改进[EB/OL].(2006-11-16)[2025-08-03].http://www.paper.edu.cn/releasepaper/content/200611-445.点此复制

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