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电弧喷涂镍基涂层组织与高温氧化行为研究

Microstructure and high-temperature oxidation behavior of Ni-based coating by wire-arc spraying

中文摘要英文摘要

为提高垃圾焚烧炉过热器的耐高温氧化和抗磨损性能,设计了两种不同B含量的NiCrB系粉芯丝材,并采用电弧喷涂技术在SA213-T2基体表面制备相应涂层,系统表征了其微观组织结构、抗高温氧化性能及显微硬度,并与商用NiCrTi涂层进行对比研究。结果表明所制备的NiCrB涂层具有热喷涂典型的层状结构,组织较为均匀致密,孔隙率约为3%,氧化物含量较低,涂层的显微硬度显著高于商用NiCrTi涂层。NiCrB涂层在800℃下的氧化增重量明显低于基体,其中B含量较低的NiCrB涂层氧化动力学曲线呈典型的抛物线形式,表面生成了连续致密的Cr2O3氧化膜,有效阻止了氧气向涂层内部渗透,使得其能够对基材起到较好的防护作用,抗高温氧化性能接近商用NiCrTi涂层。

In order to improve the high-temperature oxidation behavior and abrasive resistance of the heat exchanger tubes, the new NiCrB cored-wires with two different boron contents were designed and deposited coatings by wire arc spraying technology. The microstructures, high-temperature oxidation behavior and microhardness of the NiCrB coatings were investigated in comparison with the commercial NiCrTi coating. The results show that the NiCrB coatings exhibited dense lamella structures with fewer oxide inclusions than the NiCrTi coating. The porosities of all the Ni-based coatings were around 3%. The microhardness of NiCrB coatings were higher than that of NiCrTi coating, thus leading to its superior wear resistance. Thermogravimetric analysis was used to evaluate the high-temperature oxidation behavior of the Ni-based coatings at 800℃ under cyclic oxidation condition. It showed that the NiCrB coating with lower boron content exhibited a much better high-temperature oxidation resistance than that of substrate and approached to the commercial NiCrTi coating.

周正、王国红、吴旭、姚海华、王一鸣、贺定勇

材料科学金属学、热处理焊接、金属切割、金属粘接

NiCrB涂层电弧喷涂高温氧化显微硬度

NiCrB coatingwire arc sprayinghigh-temperature oxidationmicrohardness

周正,王国红,吴旭,姚海华,王一鸣,贺定勇.电弧喷涂镍基涂层组织与高温氧化行为研究[EB/OL].(2016-05-18)[2025-08-02].http://www.paper.edu.cn/releasepaper/content/201605-651.点此复制

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