不同沉积环境原油轻烃单体烃碳同位素组成特征
ompound-specific Carbon Isotope Composition of Light Hydrocarbons in Crude Oils from Different Sedimentary Environments
对塔里木盆地与吐哈盆地不同沉积环境原油进行了全烃色谱-同位素质谱检测分析,获得了不同沉积环境原油轻烃单体烃碳同位素组成,据此剖析了上述碳同位素组成的地球化学特征。研究表明,支链烷烃(2mC5、3mC5与3mC6)与环己烷(CYC6与mCYC6)碳同位素在海相油、湖相油与煤成油中呈现显著差异性。吐哈盆地煤成油由于不同盆地有机质特征不同的原因,其上述化合物碳同位素值小于塔里木盆地湖相油与煤成油。建立δ13 CmCYC6值作为海、陆相原油的典型区分标志,大于-25‰为陆相油,小于-25‰为海相油。进一步研究认为可以利用δ13 CmCYC6值较好的区分塔里木盆地海相油、湖相油与煤成油。
large number of crude oil from different sedimentary environments in Tarim and Tuha Basin were analysed by GC-IRMS. Compound-specific carbon isotope compositions of light hydrocarbons in crude oils from different sedimentary environments were investigated. It has been suggested that compound-specific carbon isotope of branched alkanes(2mC5,3mC5 and 3mC6) and cyclohexane compounds(CYC6 and mCYC6) Show significant difference in marine oil, lacustrine oil and coal-formed oil. Because of paticularity of organic matter in Tuha Basin, the δ13C of branched alkanes and cyclohexane compounds in coal-formed oils from Tuha Basin were less than lacustrine oil and coal-formed oil from Tarim Basin. Compound-specific carbon isotope composition of mCYC6 was established to distinguish between marine oil and continental oil. δ13 CmCYC6 is greater than -25‰ in continental oil and less than -25‰ in marine oil. It was adviesd that the δ13 CmCYC6 can be used to identify marine oil, lacustrine oil and coal-formed oil in Tarim Basin.
张敏、李洪波
石油天然气地质、石油天然气勘探
地球化学原油轻烃碳同位素
GeochemistryCrude oilLight hydrocarbonCarbon isotope
张敏,李洪波.不同沉积环境原油轻烃单体烃碳同位素组成特征[EB/OL].(2016-01-21)[2025-08-16].http://www.paper.edu.cn/releasepaper/content/201601-444.点此复制
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