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氮钝化对Te掺杂GaSb材料光学性质影响的研究

Effect of Nitrogen Passivation on Optical Properties of Te Doped GaSb

中文摘要英文摘要

锑化镓(GaSb)是实现高性能中红外波段激光器的重要材料。然而GaSb材料表面的化学性质活泼,具有较高的表面态密度,导致费米能级钉扎,严重影响GaSb基光电子器件的性能。而表面钝化可以有效减少表面态密度,增加材料表面发光性能,因此开展GaSb材料的表面钝化研究工作具有极其重要的意义。在本文中,利用等离子体增强原子层沉积(PEALD)系统,使用氮等离子体对Te掺杂GaSb的表面进行钝化处理,增强其发光强度。然后利用光致发光谱(PL)研究其发光性能,在室温下(300K),钝化样品的发光强度增强了4倍左右。在低温下(10K),观察到了由于Te施主掺杂所导致的施主-受主对(DAP)的跃迁发光,峰位位置在0.772 eV(1606nm);还观察到了带边发光(BE)峰位随温度从0.796eV到0.723eV的变化过程。

Gallium arsenide (GaSb) is an important material to realize high performance laser in middle-infrared range. However, the surface chemical properties of GaSb material is extremely active, which has high surface state density, causes Fermi level pinning. It effects on the performance of the GaSb-based devices seriously. The surface passivation can effectively decrease the surface state density and increase the surface luminescence intensity. Therefore, it's significant to carry out the research work of surface passivation of GaSb materials. In this paper, using precisely atomic layer etching technology of Te-doped GaSb surface by nitrogen plasma in the plasma enhanced atomic layer deposition (PEALD) system, increase the luminescence intensity. The luminescence property was investigated by using PL, the PL intensity increases by a factor of 4 at room temperature.At low temperature (10 K), the donor-acceptor pair(DAP) transition due to Te donor doping was observed, with a peak position of 0.772 eV (1606 nm).In addition, the change of band edge(BE)emission with temperature from 0.796 eV to 0.723 eV was also observed.

王新伟、房丹、谷李彬、方铉、唐吉龙、容天宇、王晓华、王登魁

物理学光电子技术半导体技术

PL钝化GaSbPEALDN等离子体

PLpassivationGaSbPEALDnitrogen plasma

王新伟,房丹,谷李彬,方铉,唐吉龙,容天宇,王晓华,王登魁.氮钝化对Te掺杂GaSb材料光学性质影响的研究[EB/OL].(2017-07-18)[2025-06-15].http://www.paper.edu.cn/releasepaper/content/201707-70.点此复制

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